期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 8, 页码 1111-1113出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15778g
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资金
- European Research Council (ERC) [246837]
- Israel Science Foundation
- MINERVA Foundation
- Helen and Martin Kimmel Center of Molecular Design
The unprecedented homogeneous hydrogenation of cyclic di-esters, in particular biomass-derived glycolide and lactide, to the corresponding 1,2-diols is catalyzed by Ru(II) PNN (1) and Ru(II) CNN (2) pincer complexes under mild hydrogen pressure and (in the case of 1) neutral conditions. No racemization was observed when a chiral di-ester was used.
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