期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 61, 页码 7574-7576出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33835a
关键词
-
资金
- Deutsche Forschungsgemeinschaft [DFG RO 224/60-1]
- Emmy Noether Fellowship
- NSERC of Canada
An abnormal N-heterocyclic carbene (aNHC) has been used as a Lewis base to initiate dismutation of trichlorosilane. This report presents the reactivity differences of a normal N-heterocyclic carbene (NHC) versus aNHC with heavier group 14 elements. Three novel compounds (NHC)(2)center dot SiCl2H2 (2), aNHC center dot SiCl2H2 (3), and aNHC center dot GeCl2 (4) have been synthesized and characterized by single crystal X-ray analysis, solid-state NMR and DFT calculations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据