期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 61, 页码 7559-7561出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30251a
关键词
-
资金
- MEXT [20111009]
- Japan Science and Technology Agency (JST), Core Research for Evolutional Science and Technology (CREST)
- Advanced Low Carbon Technology Research and Development Program (ALCA)
A novel dodeca-ligated undecagold cluster having a nonagold core plus two exo-attached gold atoms was synthesized. Unlike the conventional icosahedron-based core-only isomer, the [9 + 2] cluster showed an intense visible absorption band. Theoretical calculation showed the involvement of the exo gold atoms in the generation of the unique electronic structure.
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