期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 50, 页码 6256-6258出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32500d
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资金
- Johns Hopkins University
The synthesis of new boron-containing acenes (meta-B-entacenes) is reported. These compounds exhibit slightly non-planar core geometries with blue-shifted spectral properties and more negative electrochemical reduction potentials relative to known para isomers. Polarizable pi-extended architectures were realized via cross-coupling procedures with chloro-functionalized precursors.
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