期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 73, 页码 9120-9122出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34578a
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Sulfur tetrafluoride and triethylamine react at low temperatures to form a 1 : 1 adduct. The unambiguous characterization of the SF4 center dot N(C2H5)(3), which is only stable at low temperature, proves the Lewis acid property of SF4 towards organic Lewis bases. The S-N bond has a length of 2.384(2) angstrom and is an archetypical example of a dative S-IV -> N bonding modality.
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