期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 66, 页码 8276-8278出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33185c
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资金
- DST, India
- CSIR, New Delhi
An unprecedented direct reductive amination of electron-deficient amines such as Cbz-, Boc-, EtOCO-, Fmoc-, Bz-, ArSO2-, Ar2PO-, etc. protected amines with aldehydes is achieved using the Re2O7 catalyst and silanes as the hydride source. Excellent regioselective mono-alkylation and chemoselective reductive-amination were observed.
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