期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 66, 页码 8186-8188出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32887a
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资金
- Deutsche Forschungsgemeinschaft
- AvH foundation
Formyl chloride (H(Cl)C=O) is unstable at room temperature and decomposes to HCl and CO. Silicon analogue of formyl chloride, silaformyl chloride IPr center dot SiH(Cl)=O center dot B(C6F5)(3) (3) (IPr = 1,3-bis(2,6-diisopropyl-phenyl)imidazol-2-ylidene), was stabilized by Lewis donor-acceptor ligands. Compound 3 is not only the first stable acyclic silacarbonyl compound but also the first silacarbonyl halide reported so far.
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