期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 15, 页码 2146-2148出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc15665b
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资金
- NSFC [40902014]
- CPSF [20080430918]
- HIT.NSRIF [200811]
We report the enzyme-like reversible amination of four intermediates pertinent to the reductive tricarboxylic acid cycle on a photo-irradiated surface of mineral sphalerite (ZnS). Given its prevalence in the waters of early Earth, we suggest that the mineral-based photochemistry might have catalyzed the homeostasis of prebiotic metabolic systems.
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