A highly porous metal-organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake

A highly porous metal-organic framework Cu-2(BBCDC) (BBCDC = 9,9'-([1,1'-(b) under bar iphenyl]-4,4'-diyl)(b) under bar is(9H-(c) under bar arbazole-3,6-(d) under bari (c) under bar arboxylate) (DUT-49) with a specific surface area of 5476 m(2) g(-1), a pore volume of 2.91 cm(3) g(-1), a H-2 excess uptake of 80 mg g(-1) (77 K, 50 bar), a CO2 excess uptake of 2.01 g g(-1) (298 K, 50 bar) and an exceptionally high excess methane storage capacity of 308 mg g(-1) (298 K, 110 bar) was obtained using an extended tetratopic linker.