4.7 Article

The electrochemical detection of tagged nanoparticles via particle-electrode collisions: nanoelectroanalysis beyond immobilisation

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CHEMICAL COMMUNICATIONS
卷 48, 期 19, 页码 2510-2512

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17481b

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The use of particle-impact coulometry in identifying and quantifying nanoparticles tagged (or labelled) with electroactive molecules is demonstrated via the detection of 1,4-nitrothiophenol-tagged silver nanoparticles in aqueous dispersion at potentials more negative than 0.17 V (vs. Ag/AgCl, the reduction potential of nitrothiophenol) via monitoring of particle-electrode collisions.

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