期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 26, 页码 3188-3190出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17919a
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资金
- MIUR (Rome)
- Swiss National Fund
Poly(methylhydrosiloxane) (PMHS) supported organic catalysts promoted the Diels-Alder reaction of dienes with alpha,beta-unsaturated aldehydes, also in pure water, in yields and enantiomeric excesses comparable to those observed with the non-supported catalysts (up to 93% ee). Recycling of the catalysts was performed with no loss of enantioselectivity for at least five reaction cycles.
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