期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 52, 页码 6565-6567出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32214e
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资金
- National Basic Research Program of China [2010CB923402]
- NSF of Jiangsu Province [BK2009009]
- NSF of China [90922006]
- NSFC for Creative Research Group [21021062]
By using an asymmetrical 2-carboxyphenylphosphonate ligand (2-cpp(3-)), a chiral layered vanadium compound (VO)(3)(2-cpp)(2)(H2O)(6)center dot H2O (1) is isolated. The bulk sample is enantioenriched due to symmetry breaking on crystallization. Partial release of the coordination water molecules upon heating leads to a single-crystal-to-single-crystal transformation to compound [(VO)(3)(2-cpp)(2)(H2O)(4)] (1a) which is centrosymmetric.
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