期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 74, 页码 9248-9250出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32992a
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资金
- Spanish MICINN [CTQ2011-23121]
- Generalitat de Catalunya [2009SGR637]
- CNRS (France)
- Universitat de Girona (UdG)
Phosphorus dendrimers containing terminal phosphoramidite ligands have been found to be highly effective and recoverable catalysts for the rhodium(I) catalyzed [2 + 2 + 2] cycloaddition reactions. A strong positive dendritic effect is observed both in the activity and enantiodiscrimination leading to axially chiral biaryl compounds.
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