4.7 Article

Solvent-induced intercluster rearrangements and the reversible luminescence responses in sulfide bridged gold(I)-silver(I) clusters

期刊

CHEMICAL COMMUNICATIONS
卷 48, 期 69, 页码 8691-8693

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33446a

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资金

  1. Natural Science Foundation of China [21125102, 20973135, 90922011, 21021061]

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Blue or yellow-green emission is observed from two different crystal types of the same gold(I)-silver(I) molecular cluster [SAu3Ag(L1)(3)](BF4)(2) (L1 = 2-diphenylphosphino-4-methylpyridine) depending on the crystallization conditions; structural data suggest that intermolecular Au center dot center dot center dot Au interactions account for the luminescence vapochromic responses; a similar observation was made on two other pairs of analogues.

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