期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 69, 页码 8634-8636出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34150f
关键词
-
资金
- BMBF [02 NUK 012C]
- DFG [SFB 583, ME1754/2-1]
The new neopentyl (Neop)-substituted tris(aryloxide) U(III) complex [(((ArO)-Ar-Neop,Me)(3)tacn)U-III] reacts with CO2 to form CO and the bridging carbonate complex [{(((ArO)-Ar-Neop,Me)(3)tacn)U-IV}(2)(mu-CO3)]. The uranium(IV) bridging oxo [{(((ArO)-Ar-Neop,Me)(3)tacn)U-IV}(2)(mu-O)] has been determined to be the intermediate in this reaction. For the first time, both U(IV) complexes can be reduced back to the U(III) starting material. Thus, with KC8 as reductant, [(((ArO)-Ar-Neop,Me)(3)tacn)U-III] engages in a synthetic cycle, in which CO2 is converted to CO and CO32-.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据