4.7 Article

Two-photon fluorescent microporous bithiophene polymer via Suzuki cross-coupling

期刊

CHEMICAL COMMUNICATIONS
卷 48, 期 76, 页码 9519-9521

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34535h

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资金

  1. Natural Science Foundation of China [21073154]
  2. Hebei Natural Science Foundation [B2010001130]
  3. Hebei Preferred Scientific Project for Returned Visiting Scholars [20100304]
  4. National Basic Research Programs of China (973 programs) [2012CB932504]

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A microporous bithiophene polymer (MBP) stable up to 460 degrees C was synthesized using bithiophene and biphenyl as building blocks through Suzuki cross-coupling. The as-obtained MBP product exhibits green fluorescence peaked at 530 nm, and most interestingly, a two-photon fluorescence was observable from MBP upon excitation by an 800 nm femtosecond laser.

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