4.7 Article

Highly efficient double-carbonylation of amines to oxamides using gold nanoparticle catalysts

期刊

CHEMICAL COMMUNICATIONS
卷 48, 期 96, 页码 11733-11735

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36636c

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资金

  1. JSPS KAKENHI [23686116, 10J01438]
  2. Grants-in-Aid for Scientific Research [22360339, 23686116, 10J01438, 23360357, 23656512] Funding Source: KAKEN

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Hydrotalcite-supported gold nanoparticles (Au/HT) catalyzed the highly efficient double-carbonylation of amines to oxamides under mild reaction conditions. Various amines were selectively converted to the corresponding oxamides. The cooperation between gold nanoparticles and basic sites of HT plays a key role in the reaction.

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