期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 52, 页码 6478-6480出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc18116a
关键词
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资金
- MEXT, Japan [22108510, 23750148]
- JSPS
- Grants-in-Aid for Scientific Research [11J09875, 23750148, 22108510, 09J09162, 23655032, 24108712] Funding Source: KAKEN
Pendant rotaxane switch-tethering poly(m-phenylene diethynylene) was synthesized by the polyoxidative coupling of a rotaxane containing an axle-terminal m-diethynylbenzene group and an optically active crown ether. The reversible helix-random coil transition of the polymer was successfully performed by the positional switching of the rotaxane wheel.
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