期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 10, 页码 1478-1480出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc16725a
关键词
-
The first catalytic enantioselective 1,2-addition of Grignard reagents to ketones is presented. This additive-free copper(I) catalyzed 1,2-addition provides chiral allylic tertiary alcohols with an er of up to 98 : 2 and excellent yields due to the complete shift of overwhelming 1,4-selectivity of copper(I)-catalysts towards 1,2-selectivity in the addition reaction to enones.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据