期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 42, 页码 5172-5174出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/C2CC30812F
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资金
- NSFC [21172237, 21121062, 21032007]
- Major Basic Research Development Program of China [2010CB833300]
- Chinese Academy of Sciences
The Ir(I) complexes of chiral spiro phosphino-oxazoline ligands (SpinPhox) have demonstrated good to excellent enantioselectivity in the asymmetric hydrogenation (AH) of a variety of (E)-beta,beta-disubstituted alpha,beta-unsaturated N-methoxy-N-methylamides, affording the corresponding optically active Weinreb amides with up to 97% ee.
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