期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 43, 页码 11822-11839出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12318a
关键词
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资金
- National Natural Science Foundation of China [20801052, 90921013]
- CAS
- Scientific Research Foundation for the Returned Overseas Chinese Scholars of Ministry of Education [[2010]609]
- Anhui Municipal Education Commission [2009Z029]
- National Basic Research Program of China [2010CB923300, 2011CB921401]
Clusterfullerenes represent a novel branch of endohedral fullerenes, which are characterized by a robust fullerene cage with metal clusters encaged in its hollow. Since the discovery of nitride clusterfullerenes (NCFs) in 1999, the family of clusterfullerenes has been significantly expanded within the past decade, with new members including carbide clusterfullerenes (CCFs), hydrocarbide clusterfullerenes (HCCFs), oxide clusterfullerenes (OCFs), sulfide clusterfullerenes (SCFs), and carbonitride clusterfullerenes (CNCFs). We first present the classification of clusterfullerenes and list all the clusterfullerenes reported to date. For each type of clusterfullerenes, we review in detail their synthesis, separation, intriguing molecular structures and properties. For NCFs, as the first and most important clusterfullerenes, we point out the significance of their discovery and focus on their new synthesis and separation methods as well as the new advances. Finally the potential applications of clusterfullerenes are addressed. We conclude that clusterfullerenes appear to be the fastest growing family of endohedral fullerenes up to now, and emphasize the importance of exploring new structures and chemical functionalizations of clusterfullerenes.
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