期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 30, 页码 8667-8669出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12728d
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资金
- King Abdullah University of Science and Technology (KAUST) [KUS-I1-011-21]
- Department of Energy [DE-FOA-0000096]
A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions.
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