4.7 Article

Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

期刊

CHEMICAL COMMUNICATIONS
卷 47, 期 38, 页码 10587-10589

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14186d

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资金

  1. EPSRC
  2. Royal Society
  3. Engineering and Physical Sciences Research Council [EP/H006893/1] Funding Source: researchfish
  4. EPSRC [EP/H006893/1] Funding Source: UKRI

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Pentametallic Ln complexes of formula [Ln(5)O((OPr)-Pr-i)(13)] have been made, where Ln(III) = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.

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