期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 35, 页码 9764-9772出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12048d
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资金
- Australian Research Council
p-Phosphonic acid calix[n] arenes and their O-alkylated lower rim analogues are remarkably versatile macrocycles, with applications in selective diameter uptake of single walled carbon nano-tubes, as surfactants in stabilising and protecting nano-particles and graphene sheets, as crystal growth modifiers for inorganic systems, in encapsulating molecules of anti-cancer carboplatin, self assembly into nano-arrays, including nano-fibres and molecular capsules, and for binding metal ions including biologically relevant Ca2+. They are readily accessible via five or six high yielding steps from the parent p-Bu-t substituted compounds.
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