期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 24, 页码 6846-6848出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11850a
关键词
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资金
- Korean Government [NRF-2010-0016654]
- Grants-in-Aid for Scientific Research [23245029] Funding Source: KAKEN
Iron(II) complexes of Z- and E-2,6-di(1H-pyrazol-1-yl)-4-styrylpyridine (Z-2 and E-2, respectively) exhibited visible light photoisomerization from Z-2 to E-2, both in solution and in solid phases. Z-2 occupied the high-spin state over the full temperature range examined, whereas E-2 displayed a spin crossover phenomenon between 100 K and 300 K.
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