期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 1, 页码 221-223出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c002435j
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资金
- Ministry of Science, Research and the Arts of Baden-Wurttemberg [Az. 31-655.042-4-1/1]
- Ramon y Cajal
We report on the utility of multifunctional, kappa(1) Si:kappa S-3-coordinated tris(methimazolyl)silanide ligands [Si(mt(Me))(3)](-) for the stabilisation of a triangulo palladium cluster [Pd-3{Si(mt(Me))(3)}(2)] (3) consisting of very unusual mu(3)-capping SiR3 donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.
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