期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 8, 页码 2342-2344出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04120c
关键词
-
资金
- Department of Energy [DE-FG02-04ER63786]
The low reactivity of peptide-prolyl-thioesters in native chemical ligation is not due to steric effects at the beta-carbon, but rather to the presence of a carbonyl moiety on the nitrogen atom of the proline.
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