期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 5, 页码 1491-1493出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04412a
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资金
- National Natural Science Foundation of China [20772029]
- Program for New Century Excellent Talents in University [NCET-07-0286]
- Fundamental Research Funds for the Central Universities
Chiral organophosphine-catalyzed enantioselective Rauhut-Currier reaction has been disclosed for the first time. With L-valine-derived phosphinothiourea, the intramolecular Rauhut-Currier reaction of bis(enones) was achieved in good yields (up to 99%) with excellent enantioselectivities (up to 99.4% ee).
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