期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 3, 页码 1015-1017出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03164j
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资金
- Institut de Chimie des Substances Naturelles
- Agence Nationale de la Recherche (ANR)
- COST action [CM0802]
Phosphine catalyzed enantioselective [3+2] cyclizations on 4-substituted 2,6-diarylidenecyclohexanones and 2,4-diarylidene-bicyclo[3.1.0]hexan-3-ones take place with high diastereo- and enantioselectivity levels. The process affords spirocyclic compounds with excellent stereochemical control of up to five stereogenic centres.
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