期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 27, 页码 7815-7817出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12212f
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资金
- NIH [R01 GM084254]
- UCSB
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM084254] Funding Source: NIH RePORTER
The first gold-catalyzed addition of N-arylhydroxylamines to aliphatic terminal alkynes is developed to access O-alkenyl-N-arylhydroxylamines, which undergo facile in situ sequential 3,3-rearrangements and cyclodehydrations to afford 2-alkylindoles with regiospecificity and under exceptionally mild reaction conditions.
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