期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 25, 页码 7152-7154出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12162f
关键词
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资金
- University of Bayreuth
- Deutsche Forschungsgemeinschaft [WE 3546_4-1]
- Fonds der Chemischen Industrie
- IAP-VI [P6/17]
- INANOMAT
- FNRS [FRFC 2.4508.08]
- ARC-Academie Louvain
A novel iron(II) mononuclear spin transition complex [FeL(py)(2)] displays an abrupt spin transition around 225 K accompanied by a very wide thermal hysteresis loop (similar to 50 K) that spreads out over 100 K. Crystal structure analysis in both low-spin and high-spin states reveals a lipid layer-like arrangement of the complex molecules and provides insights into the spin switching mechanism.
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