期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 20, 页码 5831-5833出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10168d
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资金
- National Science Council of Taiwan [NSC 98-2911-I-259-002]
- Institut Universitaire de France (IUF)
- French-Taiwanese ORCHID [19667PA]
The first elemental cluster with hexacapped trigonal bipyramidal geometry is revealed in the luminescent undecanuclear silver complex which is stabilized by nine dithiocarbamate ligands and has an interstitial hydride. The hydride position within the Ag(11) cage is confirmed by a DFT investigation.
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