期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 14, 页码 4111-4113出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10236b
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资金
- EPSRC
- University of Oxford
- Engineering and Physical Sciences Research Council [EP/F00186X/1] Funding Source: researchfish
- EPSRC [EP/F00186X/1] Funding Source: UKRI
Reaction of K3P7, FeCl2, [NH4][B(C6H5)(4)] and 2,2,2-crypt yielded the unprecedented cluster dianion [Fe(HP7)(2)](2-). This species was characterized by single crystal X-ray diffraction, multi-element NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion were also conducted.
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