期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 26, 页码 7377-7379出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11752a
关键词
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资金
- NSF of China [20803024, 20936001, 21073065]
- Ministry of Education of China [200805611045]
- Guangdong Natural Science Foundation [10351064101000000]
- Fundamental Research Funds for the Central Universities [2009ZZ0023, 2011ZG0009]
- program for New Century Excellent Talents in Universities [NCET-08-0203]
The introduction of hydrophobic groups (e.g. methyl) at the most adjacent sites of each and every coordinating nitrogen atom of the bipyridine pillar linker in a carboxylate-based bridging MOF could shield the metal ions from attack by water molecules, and thus enhance the water resistance of the MOF structure significantly.
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