期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 17, 页码 4968-4970出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc00030f
关键词
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资金
- US Department of Energy (DOE) [DE-SC0001015, DE-FC36-07GO17033, DE-AR0000073]
- National Science Foundation (NSF) [CBET-0930079, CHE-0911207]
- Welch Foundation [A-1725]
- NSF/DOE [CHE-0535644]
- U. S. DOE, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
A super-paddlewheel (comprised of two paddlewheels) metal-organic polyhedron (MOP) containing surface hydroxyl groups was synthesized and characterized. Condensation reactions with linear alkyl anhydrides lead to new MOPs with enhanced solubility. As a result, the surface-modified MOP 4 was demonstrated as a homogeneous Lewis-acid catalyst.
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