期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 44, 页码 12224-12226出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15781g
关键词
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资金
- National Natural Science Foundation of China [20932002, 21172076]
- National Basic Research Program of China (973 Program) [2011CB808600]
- Ministry of Education of China [20090172110014]
- Guangdong Natural Science Foundation [10351064101000000]
Pd-catalysed direct oxidative carbonylation of allylic C-H bonds with carbon monoxide was first described. This new procedure shows that the inherent requirement for a leaving group in the Tsuji-Trost palladium-catalysed allylic carbonylation can be lifted, which provides a new route for accessing more synthetically useful beta-enoic acid esters with high regioselectivity.
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