4.7 Article

Direct observation of hexamethylbenzenium radical cations generated during zeolite methanol-to-olefin catalysis: an ESR study

期刊

CHEMICAL COMMUNICATIONS
卷 47, 期 33, 页码 9498-9500

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13153b

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资金

  1. National Research Foundation of Korea [2010-0029626, R0A-2007-000-20050-9]

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The generation of hexamethylbenzenium radical cations as the key reaction intermediate in chabazite-type molecular sieve acids (i.e., H-SAPO-34 and H-SSZ-13) during the methanol-to-olefin process has been directly evidenced by ESR spectroscopy.

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