4.7 Article

Palladium-catalyzed C-H bond functionalization of C6-arylpurines

期刊

CHEMICAL COMMUNICATIONS
卷 47, 期 19, 页码 5608-5610

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11135c

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资金

  1. National Nature Science Foundation of China [20802016, 21072047]
  2. Ministry of Education [NCET-09-0122]
  3. Excellent Youth Foundation of Henan Scientific Committee [114100510012]

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A highly regioselective Pd-catalyzed C(Ar)-H bond activation method was developed for the modification of purines (nucleosides) with different functional groups by using purine as a directing group. This approach provides a new access to a variety of functionalized purines (nucleosides) which are potentially of great importance in medicinal chemistry.

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