期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 27, 页码 7626-7628出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12689j
关键词
-
资金
- Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [KC020105-FWP12152]
- DOE [DE-AC05-76RL01830]
Cucurbit[7]uril (CB[7]), in its amorphous solid state, shows one of the highest CO2 sorption capacities among known organic porous materials at 298 K and 0.1 and 1 bar. In addition to the highest CO2 capacity, CB[7] also shows remarkable selectivity of CO2 over N-2 and CH4. These properties, along with the existence of readily available precursors, indicate amorphous CB[7] might find applications in recycling CO2 particularly considering the easy synthesis and potentially low manufacturing costs.
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