期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 39, 页码 11044-11046出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13775a
关键词
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资金
- Department of Science and Technology, India [SR/S1/IC-02/2009]
- Board of Research in Nuclear Sciences, India [2010/37C/3/BRNS]
- Department of Science and Technology (New Delhi)
- Engineering and Physical Sciences Research Council [EP/J003921/1] Funding Source: researchfish
- EPSRC [EP/J003921/1] Funding Source: UKRI
This work presents the first combined experimental and computational study that gives evidence of the electrophilic reactivity of a nonheme iron(III)-hydroperoxo species. We show that in contrast to their heme counterparts the nonheme iron(III)-hydroperoxo complexes are catalytically much more active and even more so than nonheme iron(IV)-oxo species.
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