期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 12, 页码 3562-3564出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05646d
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资金
- National Science Council, Taiwan [NSC98-2119-M-005-002-MY3]
A novel domino reaction, alkyne-mediated domino hydroformylation/double cyclization, has been developed for rapid preparation of indolizidine type alkaloids. DFT calculations were applied for rationales of reactivity and selectivity. A concise synthesis of tashiromine as the application of the methodology is also reported.
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