期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 28, 页码 7974-7976出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12720a
关键词
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资金
- EPSRC
- EPSRC National Mass Spectrometry Service, Swansea
- EastChem
- EPSRC [EP/I003479/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/I003479/1] Funding Source: researchfish
Oxime carbonates were found to be excellent precursors for the clean and direct generation of iminyl radicals under UV irradiation. Suitably functionalised iminyls underwent cyclisations yielding various phenanthridines and also substituted quinolines and isoquinolines. EPR and X-ray analyses of oxime carbonates provided insight into the mechanism.
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