4.7 Article

Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands

期刊

CHEMICAL COMMUNICATIONS
卷 47, 期 37, 页码 10257-10259

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13632a

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资金

  1. NIH [R01-GM67163/SSS, F32-GM087890/ANC]
  2. Camille and Henry Dreyfus Postdoctoral Program in Environmental Chemistry
  3. NSF [CHE-0946901]
  4. NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM067173, F32GM087890] Funding Source: NIH RePORTER

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Palladium-catalyzed aerobic oxidative cross-couplings of indoles and benzene have been achieved by using 4,5-diazafluorene derivatives as ancillary ligands. Proper choice of the neutral and anionic ligands enables control over the reaction regioselectivity.

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