期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 30, 页码 8599-8601出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12955d
关键词
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资金
- NSF [CHE-0517782, CMMI-0730826, 0087210]
- Ohio Board of Regents [CAP-491]
- YSU
- Division Of Chemistry [1048717] Funding Source: National Science Foundation
Reaction of meso-tetraphenylporpholactone with hydrazine converts the lactone moiety to an N-aminolactam. It also reduces the opposite pyrrolic moiety of both the starting material and the N-aminolactam, generating chlorin-like chlorolactone and N-aminochlorolactam, respectively. Reductive N-N cleavage of the N-aminoporpholactam generates the parent porpholactam.
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