期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 23, 页码 6671-6673出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc11256b
关键词
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资金
- Scientific Research on Innovative Areas [21108002]
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
- [21750036]
- Grants-in-Aid for Scientific Research [23245029] Funding Source: KAKEN
The relative reactivities of Zn, Al, and Sm carbenoids in the chemoselective carbene insertion reaction of heavier group 14 hydrides were studied. By variation of the reaction protocols using Sm carbenoids, insertion reaction can favour the Ge-H bonds to give Ge-alkylated derivatives in good to high yield.
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