期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 28, 页码 8058-8060出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12615f
关键词
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资金
- European Research Council (ERC) [StG 208651]
- Science Foundation Ireland
- SOLAR-H2 (EU) [212508]
- MICINN [CTQ2010-21497, CSD2006-0003]
The catalytic water oxidation activity of mononuclear ruthenium complexes comprising a pyridine-functionalized abnormal triazolylidene ligand can be adjusted by modification of the triazolylidene substituents, which is readily achieved through click-type cycloaddition chemistry, affording some of the most active ruthenium catalysts known thus far for water oxidation (TONs > 400, TOFs close to 7000 h(-1)).
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