期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 35, 页码 9798-9800出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13451e
关键词
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资金
- EU [EST 8303, COST D31]
- EPSRC
- Royal Society
- Deutsche Forschungsgemeinschaft
- EPSRC [EP/F035888/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/F035888/1] Funding Source: researchfish
Using dynamic combinatorial disulfide chemistry we have developed a new generation of neutral synthetic receptors for anions, based on a macrobicyclic peptide structure. These receptors show an exceptional affinity and selectivity for sulfate ions in aqueous solution [log K-a = 8.67 in 41 mol%( 67 volume%) acetonitrile in water]. The high affinity depends on a delicate balance between rigidity and flexibility in the structure of the receptor.
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