期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 42, 页码 11639-11640出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14765j
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-
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [21350026]
Titanocene(II)-promoted cross-coupling between (Z)-alkenyl methyl sulfones and terminal allenes produced 1,4-dienes regioselectively via the formation of 2-alkylidenetitanacyclopentanes. Preferential formation of E,Z-dienes was observed in the reaction using aryl-, amino-, and phosphinylallenes.
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