期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 2, 页码 701-703出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04260a
关键词
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资金
- US Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [KC020105-FWP12152]
- DOE by Battelle [DE-AC05-76RL01830]
A well-known organic host, tris-o-phenylenedioxycyclotriphosphazene, exists in two polymorphic guest-free forms: the thermodynamic nonporous high-density phase and the kinetic nanoporous low-density phase. Simple pressurization of the high density phase with CO2 brings a solid-state transformation to the low density phase, resulting in significant expansion of the crystal volume by 23%.
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