期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 46, 页码 12456-12458出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15330g
关键词
-
资金
- U.S. Department of Energy (DOE) [DE-AC02-98CH10886]
- Division of Chemical Sciences, Geosciences, & Biosciences, Office of Basic Energy Sciences
- DOE for funding under the BES Solar Energy Utilization Initiative
Our theoretical studies of the standard reduction potentials of the molecular complex [Co-II(dmgBF(2))(2)](0) (dmgBF(2) = difluoroboryldimethylglyoximate) in acetonitrile solution shed light on its electrocatalytic mechanism for hydrogen production. Three such mechanisms have been proposed, all proceeding through the formation of (CoH)-H-III. Our results indicate that the mechanism involving a (CoH)-H-II intermediate is the most likely.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据